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PRODUIT

Hydroperoxyde de tert-butyle

  • Nom du produit: Tert-butyl hydroperoxide
  • Autres noms: TBHP
  • N ° CAS.: 75-91-2
  • Pureté: ≥80% / 70%±1%
  • MF: C4H10O2
  • Apparence: white transparent liquid
  • Emballer: HDPE Drums
  • Certificat: OIN
  • Application: Mainly used as a radical initiator in various chemical reactions.
  • Échantillon: Disponible

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Détail du produit

Tert-butyl hydrogen peroxide, also known as tert-butanol hydrogen peroxide, est un composé organique, chemical formula C4H10O2, colorless transparent liquid, slightly soluble in water, easily soluble in ethanol, ether and other organic solvents, mainly used as catalyst, bleaching powder and deodorant, unsaturated polyester crosslinking agent, polymerization initiator, agent de vulcanisation du caoutchouc.

Paramètre du produit

Synonymes 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP, DPHP
Formule chimique C4H10O2 Numero CAS 75-91-2
Masse molaire 90.122 g·mol−1 Un numéro 3109
Quality Index
Index 1 Index 2
Contenu ≥80% 70%±1%
Tert-Butanol ≤0.5% ≤2.5%
Peroxyde de di-tert-butyle ≤15 ≤0.5
Chroma ≤40 ≤40
Active oxygen content 12.25~12.26 12.25~12.62
Physical and chemical properties
Apparence white transparent liquid
Indice de réfraction n=1,385~1,395
Densité relative density (water=1) 0.90; relative density (air=1) 2.07
Point de fusion 6 °C
Point d'ébullition 89°C (decomposition)
Point d'éclair 26.7°C
La pression de vapeur 2.27kPa/35~37°C
Acidité (pKa) 12.69
Basicity (pKb) 1.31
Indice de réfraction n20/D 1.403
Solubilité slightly soluble in water, easily soluble in most organic solvents such as alcohol and ether, and sodium hydroxide aqueous solution
La stabilité Écurie . But may explode if heated under confinement. Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants. Incompatible with reducing agents, combustible material, acides.
log P 1.23
Hazard mark 12 (organic peroxide), 7 (flammable liquid), 1 (explosive)
Condition de stockage 2-8°C

 

Application

1. Oxidation reaction: TBHP is a strong oxidizing agent that can oxidize a variety of organic compounds, including olefin, mercaptan, fatty alcohol, etc.. It is often used in oxidation reactions in organic synthesis, such as oxidizing alkanes to produce aldehydes and ketones.

2. Free radical reaction: chemical tert-butyl hydrogen peroxide can decompose under appropriate conditions to produce free radicals, thereby participating in free radical reactions. Par exemple, it can participate in mercaptan radical polymerization reactions for the synthesis of polymers and resins.

3. Catalyseur: tert-butyl hydrogen peroxide can be used as a catalyst to participate in some chemical reactions, such as oxidation reaction, double bond ring-opening reaction.

4. Synthetic intermediates: China tert-butyl hydrogen peroxide is also used as an intermediate for the synthesis of other compounds. Par exemple, it can react with tert-butyl methyl ether to produce p-tert-butyl benzenol peroxide as an intermediate for some organic synthesis reactions.

Hazard Characteristics

Hazardous characteristics flammable and strong oxidizing. When exposed to high heat, sun exposure, impact or contact with reducing agents and flammable substances such as sulfur and phosphorus, there is a danger of combustion and explosion.
Combustion (decomposition) products carbon monoxide, gaz carbonique.
Fire fighting method firefighters must operate in an explosion-proof shelter.
Extinguishing agent eau, foam, gaz carbonique, sand. Do not approach easily in case of fire. If there is a fire near the material, keep the container cool with water.

 

Utilisations multiples des produits

Il est utilisé dans la fabrication de produits chimiques,Industrie des polymères,Industrie du plastique,Industrie du caoutchouc,Industrie textile,Industrie de la construction et des matériaux de construction